By H. S. Genin, J. A. Ibers (auth.), Thomas Weber, Roel Prins, Rutger A. van Santen (eds.)
Hydrotreating catalysis with transition steel sulphides is without doubt one of the most vital parts of commercial heterogeneous catalysis. the current e-book bargains with the chemical and catalytic features of transition steel sulphides, targeting their use in hydrotreating catalysis. The book¿s 12 chapters current stories of solid-state, coordination and organometallic chemistry, floor technological know-how and spectroscopic stories, quantum chemical calculations, catalytic reviews with version and actual catalysts, in addition to refinery methods. A presentation of cutting-edge history to pertinent paintings within the box. can be utilized as an creation to the chemical and catalytic houses of transition steel sulphides in addition to a sophisticated point reference.
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Extra info for Transition Metal Sulphides: Chemistry and Catalysis
T. and Muller, A. (1991) Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines, Angew. Chern. Int. Ed. Engl. 30, 34-48; Angew. Chern. 103, 56-70. 3. MUller, A. and Diemann, E. (1987) Sulfides, in G. D. A. ), Comprehensive Coordination Chemistry, Vol. 2, Pergamon, Oxford, Chap. 1. 4. , Krickemeyer, E. and Bogge, H. (1986) [Cl7Cu5(ReS 4)f, a Hexanuclear Complex Anion with Double Cubane-like Structure, Angew. Chern. Int. Ed. Engl. 25, 990; Angew. Chern 98, 987. , Bogge, H.
4. ACTIVE SITES OF MOLYBDENUM DISULPIDDE As Chianelli et al. have noted , molybdenum disulphide is an important HDS catalyst. Thus the mechanism of its catalytic activity has been the subject of much research and also much debate (64]. , those sites where reactions take place, are not on the basal planes of MoS 2 but rather on the so-called "edge" positions [65, 66]. The basal planes are simply close-packed sulphide layers, as in Figure 2, that present only sulphur lone pairs towards the surface, and are therefore not very reactive.
8. Draganjac, M. B. (1985) Transition Metal Polysulfides: Coordination Compounds with Purely Inorganic Chelate Ligands, Angew. Chern. Int. Ed. Engl. 24, 742757; Angew. Chern. 97,745-760. 9. H. (1992) Trinuclear cuboidal and heterometallic cubane-type iron-sulfur clusters: new structural and reactivity themes in chemistry and biology, Adv. Inorg. Chern. 38, 1-71. 10. , WienbOker, U. and Bogge, H. (1989) Formation of the metal-sulfide aggregate [W3S 10t through a novel balanced intramolecular condensation redox process with principal relevance to the formation of amorphous metal sulfides like WS 3 , Inorg.