Proceedings of the Moscow Symposium on the Chemistry of by V. I. Spitsyn

By V. I. Spitsyn

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1]. t T h e s e values calculated in the present work are in general considered to be more accurate than the corresponding calculated values in parentheses from Ref. [1]. Lanthanide and actinide series applied further in a refinement of the previous E ° M ( I I I - I V ) potentials. T h e important n e w results of this w o r k are p r e s e n t e d in Tables 1 and 2 and in Figs. 1 and 2. In c o n t r a s t to our p r e v i o u s w o r k [ 1 , 2 , 8 ] , w e use t h e sign c o n v e n t i o n and n o m e n c l a t u r e for electrode potentials here as a d o p t e d by the I U P A C Council at Cortina d ' A m p e z z o , Italy, 7 July 1969 [9].

4·9±0·2 -4-9 -4-7 -4-7 -4-7 -3-5 -2-3(-2-6)*Ф -4·4(-5·0)*·φ -2·8(-3·4)*·ΐ -1·6(-1·9)*Φ — 1-3 ( - 1-6)* Φ — 1-1 ( — 1-3)* Φ 00 + 1-3 *Ref. [2]. t L . R. Morss and H. Haug, J. Chem. Thermo. 5, 513 (1973). ÍThese values from previous work (réf. 2) are in general considered to be less accurate. §H. A. Friedman, J. R. Stokely and R. D. Baybarz, Inorg. nucl. Chem. Lett. 8, 433 (1972), have recently shown that the half-wave Polarographie (III-II) reduction potentials for Sm(III) and for Cf(III) in anhydrous 0 1 M tetraethylammonium Perchlorate acetonitrile solution are essentially the same.

Am. 64, 687 (1974). K. L. Vander Sluis and L. J. Nugent, Phys. Rev. A 6 , 8 6 (1972). C. K. Jrirgensen, Molec. Phys. 5, 271 (1962). J. L. Ryan and C. K. Jrirgensen, Molec. Phys. 7, 17 (1963). C. K. Jórgensen, Chem. Phys. Lett. 2, 549 (1968). L. J. Nugent, R. D . Baybarz, J. L. Burnett and J. L. Ryan, J. Phys. Chem. 77, 1528 (1973). M. L. McGlashan, Pure appi. Chem. 21, 1 (1970). J. inorg. nucl. , S u p p l e m e n t 1976. Pergamon Press. Printed in Great Britain. OXIDATION-REDUCTION REACTIONS OF THE TRANSURANIUM ELEMENTS DONALD COHEN Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439 (Received 9 March 1974) THIS p a p e r will b e divided into three sections.

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