Electroanalytical Chemistry: A Series of Advances, Volume 27 by Allen J. Bard, Cynthia G. Zoski

By Allen J. Bard, Cynthia G. Zoski


This quantity is a part of a continuous sequence that gives authoritative experiences on contemporary advancements and functions of well-established innovations within the box of electroanalytical chemistry. each one quantity presents the required history and start line for graduate scholars project comparable examine initiatives and is of exact curiosity to working towards analytical chemists fascinated with electroanalytical ideas. quantity 27 keeps this custom with cutting edge contributions from across the world revered scientists who spotlight new applied sciences and tendencies in Protein Biosensing, Bipolar Electrochemistry, and X-ray Absorption Spectroscopy in Electrochemistry.

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Extra resources for Electroanalytical Chemistry: A Series of Advances, Volume 27

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D Chidsey, “ Clicking” functionality onto electrode surfaces, Langmuir , Vol. 20, (2004): p. 1051– 1053. 59. Canete, S. J. , W. Yang, and R. Y. Lai, Folding-based electrochemical DNA sensor fabricated by “ click” chemistry, Chem Commun , (2009): p. 4835– 4837. 60. , A. K. Udit, R. A. Evans, and M. G. Finn, Electrochemically protected copper(I)-catalyzed azide-alkyne cycloaddition, Chembiochem , Vol. 9, (2008): p. 1481– 1486. 61. Furst, A. , M. G. Hill, and J. K. Barton, A multiplexed, two-electrode platform for biosensing based on DNA-mediated charge transport, Langmuir , Vol.

6) [61,62]. In the presence of alkyne-labeled DNA, a reduction of Cu(II) at the microelectrode generates Cu(I) locally and allows for the conjugation of specific DNA sequences at precisely defined locations on the surface. Any electrochemical fouling that accompanies the Cu(II) reduction occurs at the secondary microelectrode, leaving the DNA monolayer undamaged. Importantly, this secondary electrode can also be used to report on the efficiency of DNA CT reactions at the monolayer. This new “ patterning/sensing” platform allows extremely sensitive monitoring of protein-binding events, lesions, mismatches, and hybridization; because electrochemical readout occurs at a secondary electrode, the platform enables direct comparison of multiple sequences under identical conditions, incorporating both redundancy and internal controls onto the same electrode surface.

Ghatlia, S. H. Bossmann, N. J. Turro, and J. K. Barton, Long-range photoinduced electron transfer through a DNA helix, Science , Vol. 262, (1993): p. 1025– 1029. 29. Murphy, C. , M. R. Arkin, N. D. Ghatlia, S. Bossmann, N. J. Turro, and J. K. Barton, Fast photoinduced electron transfer through DNA intercalation, Proc Natl Acad Sci USA , Vol. 91, (1994): p. 5315– 5319. 24 Electroanalytical Chemistry: A Series of Advances 30. Kelley, S. , J. K. Barton, N. M. Jackson, and M. G. Hill, Electrochemistry of methylene blue bound to a DNA-modified electrode, Bioconjug Chem , Vol.

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