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Extra info for Contrast Agents III Radiopharmaceuticals. From Diagnostics to Therapeutics
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Labelling with the fac[99mTc(CO)3]+ moiety occurs at medium to low concentration. The X-ray structures of the corresponding rhenium-complexes have been elucidated showing that the PNN ligand is tridentate and the PNO ligand bidentate. Interestingly, in the latter case the amide group coordinates through the carbonyl oxygen and not through the deprotonated NH group, representing one of the rare cases in which O is preferred over N . The same group published rare examples of pyrazol-based ligands.